Volume 30 Issue 12
Dec.  2018
Turn off MathJax
Article Contents
Li Yanglong, Wu Lingyuan, Shen Huanhuan, et al. Patterning of graphene by light field modulated nanosecond laser[J]. High Power Laser and Particle Beams, 2018, 30: 129001. doi: 10.11884/HPLPB201830.180154
Citation: Li Yanglong, Wu Lingyuan, Shen Huanhuan, et al. Patterning of graphene by light field modulated nanosecond laser[J]. High Power Laser and Particle Beams, 2018, 30: 129001. doi: 10.11884/HPLPB201830.180154

Patterning of graphene by light field modulated nanosecond laser

doi: 10.11884/HPLPB201830.180154
  • Received Date: 2018-06-01
  • Rev Recd Date: 2018-11-12
  • Publish Date: 2018-12-15
  • Laser-based approaches for graphene synthesis, reduction, modification, cutting and micro-patterning have been developed and applied to the fabrication of various electronic devices.General method utilized in direct laser writing and patterning of graphene was realized by controlling the movement of the sample or the laser reflecting mirror, while patterning by single shot laser is rarely reported.In the present study, a single shot laser patterning graphene method via light field modulating is proposed.Via controlling the light field by special light modulator (SLM), nanosecond laser pulses focused by objective lens were modulated to the desired pattern.The 4layer graphene in the laser irradiate region was damaged when laser energy was lager than 0.03 mJ.When the laser energy reached 0.06 mJ, clear pattern formed in graphene while no damage occurred in silicon base.The characteristics of graphene patterns were measured using Raman spectra imaging technology.The experimental results revealed that the light field modulated nanosecond laser remains potentially advantageous in graphene micro pattern processing with no need of moving the sample, quick processing and micrometer precision.
  • loading
  • [1]
    Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(22): 666-669.
    [2]
    Morozov S V, Novoselov K S, Katsnelson M I, et al. Giant intrinsic carrier mobilities in graphene and its bilayer[J]. Phys Rev Lett, 2008, 100: 016602. doi: 10.1103/PhysRevLett.100.016602
    [3]
    Nair R R, Blake P, Grigorenko A N, et al. Fine structure constant defines visual transparency of graphene[J]. Science, 2008, 321(6): 1308.
    [4]
    Lee C, Wei X, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science, 2008, 321(18): 385-388.
    [5]
    Krauss B, Lohmann T, Chae D H, et al. Laser-induced disassembly of a graphene single crystal into a nanocrystalline network[J]. Phys Rev B, 2009, 79: 165428. doi: 10.1103/PhysRevB.79.165428
    [6]
    Qian M, Zhou Y S, Gao Y, et al. Formation of graphene sheets through laser exfoliation of highly ordered pyrolytic graphite[J]. Appl Phys Lett, 2011, 98: 173108. doi: 10.1063/1.3584021
    [7]
    Lee S, Toney M F, Ko W, et al. Laser-synthesized epitaxial graphene[J]. ACS Nano, 2010, 4(12): 7524-7530. doi: 10.1021/nn101796e
    [8]
    Park J B, Xiong W, Gao Y, et al. Fast growth of graphene patterns by laser direct writing[J]. Appl Phys Lett, 2011, 98: 123109. doi: 10.1063/1.3569720
    [9]
    Huang L, Liu Y, Ji L C, et al. Pulsed laser assisted reduction of graphene oxide[J]. Carbon, 2011, 49(7): 2431-2436. doi: 10.1016/j.carbon.2011.01.067
    [10]
    Roberts A, Cormode D, Reynolds C, et al. Response of graphene to femtosecond high-intensity laser irradiation[J]. Appl Phys Lett, 2011, 99: 051912. doi: 10.1063/1.3623760
    [11]
    Zhou Y, Bao Q L, Varghese B N, et al. Microstructuring of graphene oxide nanosheets using direct laser writing[J]. Adv Mater, 2010, 22(1): 67-71. doi: 10.1002/adma.200901942
    [12]
    吴凌远, 李阳龙, 刘国栋, 等. 1064 nm纳秒激光对石墨烯的损伤效应研究[J]. 强激光与粒子束, 2015, 27: 081009. doi: 10.11884/HPLPB201527.081009

    Wu Lingyuan, Li Yanglong, Liu Guodong, et al. 1064 nm nanosecond laser induced damage effect on graphene. High Power Laser and Particle Beams, 2015, 27: 081009 doi: 10.11884/HPLPB201527.081009
    [13]
    Jani K, Christian B, Yigal L, et al. Toward two-dimensional all-carbon heterostructures via ion beam patterning of single-layer graphene[J]. Nano Lett, 2015, 15(9): 5944-5949. doi: 10.1021/acs.nanolett.5b02063
    [14]
    Chen Y, Zhang N, Li Y F, et al. Microscal E-patterned graphene electrodes for organic light-emitting devices by a simple patterning strategy[J]. Adv Optical Mater, 2018, 13: 1701348.
    [15]
    Ethan B S, Pradyumna L P, Kanan P, et al. Inkjet printing of high conductivity, flexible graphene patterns[J]. J Phys Chem Lett, 2013, 4(8): 1347-1351. doi: 10.1021/jz400644c
    [16]
    南洋, 张建寰, 张陈涛. 激光直写制备石墨烯研究进展[J]. 化工新型材料, 2015, 43(12): 1-3. https://www.cnki.com.cn/Article/CJFDTOTAL-HGXC201512001.htm

    Nan Yang, Zhang Jianhuan, Zhang Chentao. Progress in laser direct writing synthesis of graphene. New Chemical Materials. 2015, 43(12): 1-3 https://www.cnki.com.cn/Article/CJFDTOTAL-HGXC201512001.htm
    [17]
    Chen H Y, Han D D, Tian Y, et al. Mask-free and programmable patterning of graphene by ultrafast laserdirect writing[J]. Chemical Physics, 2014, 430: 13-17. doi: 10.1016/j.chemphys.2013.12.005
    [18]
    Chang T L, Chen Z C, Chen W Y, et al. Patterning of multilayer graphene on glass substrate by using ultraviolet picosecond laser pulses[J]. Microelectronic Engineering, 2016, 158(1): 1-5.
    [19]
    Lee K, Ki H. Fabrication and optimization of transparent conductive films using laser annealing and picosecond laser patterning[J]. Applied Surface Science, 2017, 420(1): 886-895.
    [20]
    Pechlivani E M, Papas D, Mekeridis C, et al. Ultra-short pulse laser for patterning high quality graphene electrodes[J]. Materials Today: Proceedings, 2017, 4(4): 5074-5081. doi: 10.1016/j.matpr.2017.04.116
    [21]
    Kumar R, Singh R K, Singh D P, et al. Laser-assisted synthesis, reduction and micro-patterning of graphene: Recent progress and applications[J]. Coordination Chemistry Reviews, 2017, 342: 34-79. doi: 10.1016/j.ccr.2017.03.021
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(4)

    Article views (816) PDF downloads(84) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return