Calculation of electron conductive opacity is performed in partial wave by employing extended Ziman formula with the mechanism of i e elastic scattering based on average atomic model in relativistic Hartree Fock-Slater selfconsistent field.For studying in more detail,effect of ionic types in plasmas is taken into account on electron conductive opacity.In order to get the emerging probabilities of ionic types in plasmas,the fluctuation theory of entropy and Boltzmann relation are used.