Preparation of poly(imine imine ketone)s microshells

Large diameter (0.6～2.0 mm) microshells of poly (imine imine ketone)s (PIIKs) were prepared by microliquid technique and doublelayer latex technique. A double T-channel droplet generator was designed and developed for the fabrication of PIIKs microshells of controlled size continuously. Manipulative conditions of the diameter and thickness of shells were studied, and the effect of density mismatch on shell quality was discussed. Phase separation during the preparation process affects the morphology of shells. Spinodal phase separation tends to occur at the outer surface of the shells，while binodal phase separation at the inner surface. The diameters of PIIKs shells were measured, 88% of which vary in ±5% of the average diameter. The sphericity is better than 99%．