等离子体表面梯度硅沉积对环氧树脂电气性能的影响

Effect of plasma surface gradient silicon deposition on the electrical properties of epoxy resin

  • 摘要: 环氧树脂作为常见的绝缘材料,在高压直流电场作用下易在其表面积累电荷,发生电场畸变,导致材料绝缘性能下降,影响电力系统运行可靠性。为改善气固界面的电荷特性和绝缘性能,在大气压等离子体射流技术的基础上,对环氧树脂表面进行等离子体梯度硅沉积处理。对改性前后环氧树脂表面理化特性、表面电导率、表面电荷消散和沿面耐压特性进行了多参数测量。实验结果表明,梯度改性对材料表面的物理形貌和化学组分均有明显影响,不同区域的电导率实现了梯度分布,加快了表面电荷消散速度,表面陷阱能级变浅;梯度改性后的样品沿面闪络电压提升幅度可达30.16%。通过等离子体表面梯度硅沉积处理能够改善环氧树脂表面电气性能,在高压直流设备的绝缘设计方面具有广阔的应用前景。

     

    Abstract: As a common insulating material, epoxy resin under high-voltage direct current electric field is prone to accumulate charges on its surface, causing electric field distortion, resulting in a decrease in the insulation performance of the material and affecting the reliability of the power system. To improve the charge characteristics and insulation properties of the gas-solid interface, based on the atmospheric pressure plasma jet technology, plasma gradient silicon deposition were conducted on the epoxy resin surface. The surface physical and chemical properties, surface conductivity, surface charge dissipation and creeping pressure characteristics of epoxy resin before and after modification were measured by multiple parameters. The experimental results show that the gradient modification has a significant effect on the physical morphology and chemical composition of the material surface. The conductivity of different regions has achieved a gradient distribution, which speeds up the dissipation of surface charges and reduces the surface trap energy level; The flashover voltage of the subsequent samples can increase by 30.16% along the surface. In summary, the plasma surface gradient silicon deposition treatment can improve the electrical properties of the epoxy resin surface, and has broad application prospects in the insulation design of high-voltage DC equipment.

     

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